The synthesis of triamine-bearing porous silica for the effective adsorption of nitrate and phosphate ions

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Phuoc T. Phan
Thai A. Nguyen
Nhat H. Nguyen
Long G. Bach
Phuoc S. Le
Trung T. Nguyen

Abstract

This work focuses on determining the effect of material synthesis conditions and studying on kinetic, isothermal and thermodynamic parameters of nitrate and phosphate adsorption by triamine-bearing porous silica (TRI-P- ) material. The innovation of this study is to improve the surface of  through chemical corrosion reaction with hydrofluoric acid (HF) before grafting with triamine silane. In the suitable condition of synthesis including 5% of HF concentration, and a ratio of 3 mL/g between the volume of Triamine-Silane and the weight of P- , the uptake rates of nitrate and phosphate adsorption are 33.4 and 10.8 mg/g, respectively. Moreover, the adsorption data of these ions are highly compatible with Pseudo-second-order kinetics in which values ​​of the correlation coefficients (r2) are greater than 0.99. Moreover, these adsorption processes have been well described by Langmuir and Freundlich isotherm models (r2>0.96). The nitrate and phosphate adsorption capacities are 125.0 and 112.4 mg/g, respectively. Along with the good resulting adsorption, the large number of adsorption cycles also highlight the usefulness of this material. In general, this material can be used to remove nitrate and phosphate ions in advanced feedwater and wastewater treatment processes.

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References

Vinçon-Leite B, Casenave C. Modelling eutrophication in lake ecosystems: a review. Sci Total Environ. 2019;651:2985-3001.
Essien EE, Said Abasse K, Côté A, Mohamed KS, Baig MMFA, Habib M, et al. Drinking-water nitrate and cancer risk: a systematic review and meta-analysis. Arch Environ Occup Health. 2020;3:1-17.
Ward M, Jones R, Brender J, de Kok T, Weyer P, Nolan B, et al. Drinking water nitrate and human health: an updated review. Int J Environ Res Public Health. 2018;15(7):1-31.
Park JJ, Byun IG, Park SR, Lee JH, Park SH, Park TJ, et al. Use of spent sulfidic caustic for autotrophic denitrification in the biological nitrogen removal processes: lab-scale and pilot-scale experiments. J Ind Eng Chem. 2009;15(3):316-322.
Malaeb L, Ayoub GM. Reverse osmosis technology for water treatment: state of the art review. Desalination. 2011;267(1):1-8.
Bhatnagar A, Sillanpää M. A review of emerging adsorbents for nitrate removal from water. Chem Eng J. 2011;168(2):493-504.
Prashantha Kumar TKM, Mandlimath TR, Sangeetha P, Revathi SK, Ashok Kumar SK. Nanoscale materials as sorbents for nitrate and phosphate removal from water. Environ Chem Lett. 2018;16(2): 389-400.
Nujić M, Milinković D, Habuda-Stanić M. Nitrate removal from water by ion exchange. CJFSAU. 2017; 9(2):182-186.
Hamoudi S, Saad R, Belkacemi K. Adsorptive removal of phosphate and nitrate anions from aqueous solutions using ammonium-functionalized mesoporous silica. Ind Eng Chem Res. 2007;46(25):8806-8812.
Saad R, Hamoudi S, Belkacemi K. Adsorption of phosphate and nitrate anions on ammonium-functionnalized mesoporous silicas. J Porous Mater. 2008;15(3):315-323.
Phan Phuoc Toan, Nguyen Trung Thanh, Nguyen Nhat Huy, Le Ngoc Hang, Thich LT. Characterization and adsorption capacity of amine-SiO_2 material for nitrate and phosphate removal. Vietnam J Sci Technol. 2019;57(4):484-490.
Nguyen Trung Thanh. Amine-bearing activated rice husk ash for CO2 and H2S gas removals from biogas. Eng Appl Sci Res. 2016;43(S3):396-398.
Song W, Gao B, Xu X, Wang F, Xue N, Sun S, et al. Adsorption of nitrate from aqueous solution by magnetic amine-crosslinked biopolymer based corn stalk and its chemical regeneration property. J Hazard Mater. 2016;304:280-290.
Hassan A, Youssef A. Preparation and characterization of microporous NaOH-activated carbons from hydrofluoric acid leached rice husk and its application for lead (II) adsorption. Carbon Lett. 2014;15(1): 57-66.
Safia H, Abir EN, Maissa B, Khaled B. Adsorptive removal of nitrate and phosphate anions from aqueous solutions using functionalised SBA‐15: effects of the organic functional group. Can J Chem Eng. 2012; 90(1):34-40.
Aswin Kumar I, Viswanathan N. Development and reuse of amine-grafted chitosan hybrid beads in the retention of nitrate and phosphate. J Chem Eng Data. 2018;63(1):147-158.
Tseng RL, Wu KT, Wu FC, Juang RS. Kinetic studies on the adsorption of phenol, 4-chlorophenol, and 2, 4-dichlorophenol from water using activated carbons. J Environ Manage. 2010;91(11):2208-2214.
Rajeswari A, Amalraj A, Pius A. Adsorption studies for the removal of nitrate using chitosan/PEG and chitosan/PVA polymer composites. J Water Process Eng. 2016;9:123-134.
Hu Q, Chen N, Feng C, Hu W. Nitrate adsorption from aqueous solution using granular chitosan-Fe3+ complex. Appl Surf Sci. 2015;347:1-9.
Iida T, Amano Y, Machida M, Imazeki F. Effect of surface property of activated carbon on adsorption of nitrate ion. Chem Pharm Bull. 2013;61(11):1173-1177.
Zhang B, Chen N, Feng C, Zhang Z. Adsorption for phosphate by crosslinked/non-crosslinked-chitosan-Fe (III) complex sorbents: characteristic and mechanism. Chem Eng Sci. 2018;353:361-372.
Wang Z, Guo H, Shen F, Yang G, Zhang Y, Zeng Y, et al. Biochar produced from oak sawdust by lanthanum (La)-involved pyrolysis for adsorption of ammonium (NH_4^+), nitrate (NO_3^-), and phosphate (PO_4^(3-)). Chemosphere. 2015;119:646-653.
Wu FC, Tseng RL, Juang RS. A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals. J Environ Manage. 2010;91(4):798-806.
Turabik M. Adsorption of basic dyes from single and binary component systems onto bentonite: simultaneous analysis of basic red 46 and basic tellow 28 by first order derivative spectrophotometric analysis method. J Hazard Mater. 2008;158(1):52-64.
Dursun AY, Kalayci CS. Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto chitin. J Hazard Mater. 2005;123(1-3):151-157.
Ganesan P, Kamaraj R, Vasudevan S. Application of isotherm, kinetic and thermodynamic models for the adsorption of nitrate ions on graphene from aqueous solution. J Taiwan Inst Chem E. 2013;44(5):808-814.
Kamaraj R, Pandiarajan A, Jayakiruba S, Naushad M, Vasudevan S. Kinetics, thermodynamics and isotherm modeling for removal of nitrate from liquids by facile one-pot electrosynthesized nano zinc hydroxide. J Mol Liq. 2016;215:204-211.
Katal R, Baei MS, Rahmati HT, Esfandian H. Kinetic, isotherm and thermodynamic study of nitrate adsorption from aqueous solution using modified rice husk. J Ind Eng Chem. 2012;18(1):295-302.
Wu Y, Wang Y, Wang J, Xu S, Yu L, Philippe C, et al. Nitrate removal from water by new polymeric adsorbent modified with amino and quaternary ammonium groups: batch and column adsorption study. J Taiwan Inst Chem Eng. 2016;66:191-199.
Mezenner NY, Bensmaili A. Kinetics and thermodynamic study of phosphate adsorption on iron hydroxide-eggshell waste. Chem Eng J. 2009;147(2):87-96.
Yoon SY, Lee CG, Park JA, Kim JH, Kim SB, Lee SH, et al. Kinetic, equilibrium and thermodynamic studies for phosphate adsorption to magnetic iron oxide nanoparticles. Chem Eng J. 2014;236:341-347.
Zhang L, Jin S, Wang Y, Ji J. Phosphate adsorption from aqueous solution by lanthanum-iron hydroxide loaded with expanded graphite. Environ Technol. 2018;39(8):997-1006.
Qiu H, Ni W, Zhang H, Chen K, Yu J. Fabrication and evaluation of a regenerable HFO-doped agricultural waste for enhanced adsorption affinity towards phosphate. Sci Total Environ. 2020;703:135493.
Saad R, Belkacemi K, Hamoudi S. Adsorption of phosphate and nitrate anions on ammonium-functionalized MCM-48: effects of experimental conditions. J Colloid Interface Sci. 2007;311(2):375-381.
Ebrahimi-Gatkash M, Younesi H, Shahbazi A, Heidari A. Amino-functionalized mesoporous MCM-41 silica as an efficient adsorbent for water treatment: batch and fixed-bed column adsorption of the nitrate anion. Appl Water Sci. 2017;7(4):1887-1901.