Adsorption of PM2.5 emissions from laser printer by paper waste aerogel

Main Article Content

Nanthana Chanthorn
Thanathorn Petchrat
Titiwud Pongtanapaisan
Sirikarn Thongmai
Thanakrit Neamhom

Abstract

Paper waste, rich in cellulose fibers have become recycled material for pollutant adsorption. This work investigated the feasibility of using aerogel produced from paper waste to capture particulate matter (PM2.5) particles emitted from laser printer devices during their printing job. This study also determined the adsorption behavior using an appropriate isotherm model in the batch process. The preparation conditions for adsorbent aerogel included 3 types of paper waste (2-used sided paper; 2P, color and newspaper), the pretreatment process and production procedures for waste paper aerogel (WPA) and waste paper/chitosan aerogel (WP-CSA). Experiments were conducted in a simulated chamber under actual printing environmental conditions. The results showed that (1) the paper-based aerogels were capable of capturing particle emissions from the printing, (2) the pretreatment process played a significant role in adsorption capacity and (3) the aerogel obtained from 2P without treatment and WPA process showed the best removal efficiency, up to 12 μg/m3 or 63.2% compared with baseline. At equilibrium, this adsorption process obeyed the Freundlich model with an R2 value of 0.83. This implied that the adsorption sites on the aerogel surface were heterogeneous in nature and presented a strong interaction between PM2.5 and adsorbent fibers. They revealed a maximum adsorption capacity of 0.002 mg/g. Overall, this conversion, an environmentally friendly alternative to reuse paper waste, showed excellent adsorption capacity and reduced health risks from exposure to PM2.5 from laser printer devices.

Article Details

How to Cite
Chanthorn, N., Petchrat, T., Pongtanapaisan, T. ., Thongmai, S., & Neamhom, T. (2023). Adsorption of PM2.5 emissions from laser printer by paper waste aerogel. Asia-Pacific Journal of Science and Technology, 28(02), APST–28. https://doi.org/10.14456/apst.2023.31
Section
Research Articles

References

Lee J, Koo JW. Occupational diseases among office workers and prevention strategies. J Ergon Soc Korea. 2015;34(2):125-134.

U.S. Environmental Protection Agency. An office building occupant’s guide to indoor air quality, https://www.epa.gov/sites/production /files/2014-08/documents/occupants_guide.pdf [accessed 16 March 2020].

Park JH, Schleiff PL, Attfield MD, Cox-Ganser JM, Kreiss K. Building-related respiratory symptoms can be predicted with semi-quantitative indices of exposure to dampness and mold. Indoor Air. 2004;14:425-433.

Stenberg B, Eriksson N, Höög J, Sundell J, Wall S. The sick building syndrome (Sbs) in office workers. a case-referent study of personal, psychosocial and building-related risk indicators. Int J Epidemiol. 1994;23(6):1190-1197.

Nordström K, Norbäck D, Wieslander G. Subjective indoor air quality in geriatric hospitals. Indoor Built Environ. 1999;8(1):49-57.

U.S. Environmental Protection Agency. Indoor Particulate Matter, https://ww w.epa.gov/indoor-air-quality-iaq/indoor-particulate-matter [accessed 4 February 2020].

Saramak A. Comparative analysis of indoor and outdoor concentration of PM10 particulate matter on example of Cracow City Center. Int J Environ Sci Technol. 2019;16(11):6609-6616.

California Environmental Protection Agency. Inhalable Particulate Matter and Health (PM2.5 and PM10), https://ww2.arb.ca.gov/resources/inhalable-particulate-matter-and-health [accessed 18 April 2021].

Seppänen OA. Association of ventilation rates and CO2 concentrations with health and other responses in commercial and institutional buildings. Indoor Air. 1999;9(4):226-252.

Umoh VA, Peters E. The relationship between lung function and indoor air pollution among rural women in the Niger Delta region of Nigeria. Lung India. 2014;31(2):110-115.

Ari A. A comprehensive study on gas and particle emissions from laser printers: chemical composition and health risk assessment. Atmos Pollut Res. 2020;11(2):269-282.

Tang T, Hurraß J, Gminski R, Sundermann MV. Fine and ultrafine particles emitted from laser printers as indoor air contaminants in German offices. Environ Sci Pollut Res. 2012;19(9):3840-3849.

Zou C, Yang H, Cui L, Cao X, Huang H, Chen T. Potential hazardous effects of printing room PM2.5 exp osure include promotion of lung inflammation and subsequent injury. Mol Med Rep. 2020;22(4):3213-2324.

Mullins BJ, Bertolatti D, Mead-Hunter R. Assessment of polyaromatic hydrocarbon emissions from laser printers. Atmos Environ. 2013;79:428-432.

Li Z, Shao L, Ruan Z, Hu W, Lu L, Chen Y. Converting untreated waste office paper and chitosan into aerogel adsorbent for the removal of heavy metal ions. Carbohydr Polym. 2018;193:221-227.

Li Z, Jia Z, Ni T, Li S. Adsorption of methylene blue on natural cotton based flexible carbon fiber aerogels activated by novel air-limited carbonization method. J Mol Liq. 2017;242:747-756.

Lovskaya D, Menshutina N, Mochalova M, Nosov A. Chitosan-based aerogel particles as highly effective local hemostatic agents. production process and In Vivo evaluations. Polymers. 2020;12:1-12.

Rinki K, Dutta PK, Hunt AJ, MacQuarrie DJ, Clark JH. Chitosan aerogels exhibiting high surface area for biomedical application: preparation, characterization, and antibacterial study. Int J Polym Mater Polym Biomater. 2011;60(12):988-999.

Zhao X, Zeng X, Qin Y, Li X, Zhu T, Tang X. An experimental and theoretical study of the adsorption removal of toluene and chlorobenzene on coconut shell derived carbon. Chemosphere. 2018;206:285-292.

Hoyos-Sánchez MC, Córdoba-Pacheco AC, Rodríguez-Herrera LF, Uribe-Kaffure R. Removal of Cd (II) from aqueous media by adsorption onto chemically and thermally treated rice husk. J Chem. 2017;5763832:1-8.

Li Z, Shao L, Hu W, Zheng T, Lu L, Cao Y, et al. Excellent reusable chitosan / cellulose aerogel as an oil and organic solvent absorbent. Carbohydr Polym. 2018;191:183-190.

Porubska M, Jomová K, Branisa J. Analysis of natural materials’ adsorption efficiency relating Co (II) using atomic absorption spectroscopy: laboratory experiment. J Chem Educ. 2021;98(2):626-232.

Ndi Nsami J, Ketcha Mbadcam J. The adsorption efficiency of chemically prepared activated carbon from cola nut shells by ZnCl2 on methylene blue. J Chem. 2013;469170:1-7.

Alvarez NM, Pastrana JM, Lagos Y, Lozada JJ. Evaluation of mercury (Hg2+) adsorption capacity using exhausted coffee waste. Sustain Chem Pharm. 2018;10:60-70.

Santasnachok C, Kurniawan W, Hinode H. The use of synthesized zeolites from power plant rice husk ash obtained from Thailand as adsorbent for cadmium contamination removal from zinc mining. J Environ Chem Eng. 2015;3(3):2115-2126.

Claudio E, Luiz G, Ben A. Adsorption of amoxicillin and paracetamol on modified activated carbons: equilibrium and positional entropy studies. 2017;234:375-381.

Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc. 1918;40(9):1361-1403.

Freundlich H. Uber die adsorption in losungen. Z Phys Chem (NF). 1906;54:385-470.

Bang SY, Kim JH. Isotherm, kinetic, and thermodynamic studies on the adsorption behavior of 10-deacetylpaclitaxel onto sylopute. Biotechnol Bioprocess Eng. 2017;22(5):620-630.

Nikiforova TE, Kozlov VA. Regularities of the effects of the nature of polysaccharide materials on distribution of heavy metal ions in a heterophase biosorbent-water solution system. Prot Met Phys Chem Surfaces. 2016;52(3):243-271.

Neamhom T. Use of agricultural residues to remove iron from groundwater in modified airlift aerator. Environ Nat Resour J. 2019;17(3):58-67.

Jin C, Han S, Li J, Sun Q. Fabrication of cellulose-based aerogels from waste newspaper without any pretreatment and their use for absorbents. Carbohydr Polym. 2015;123:150-156.

Ai L, Li M, Li L. Adsorption of methylene blue from aqueous solution with activated carbon/cobalt ferrite/alginate composite beads: kinetics, isotherms, and thermodynamics. J Chem Eng Data. 2011;56(8):375-483.

Ogata F, Nakamura T, Kawasaki N. Adsorption capability of virgin and calcined wheat bran for molybdenum present in aqueous solution and elucidating the adsorption mechanism by adsorption isotherms, kinetics, and regeneration. J Environ Chem Eng. 2018;6(4):4459-4566.

Öztürk N, Kavak D. Boron removal from aqueous solutions by batch adsorption onto cerium oxide using full factorial design. Desalination. 2008;223(1-3):106-112.