Application of metal-organic frameworks for carbon dioxide capture

Main Article Content

Apipong Putkham

Abstract

       Carbon dioxide, also known as green house gas, has a potential to cause the global warming and also climate change. Results from many researchers indicated that the earth’s surface temperature has increased about 0.6 ? C during AD 1950-2000. These changes may have a widely negative effect on ecological system and human activities all over the world. The Intergovernmental Panel on Climate Change (IPCC) suggested that carbon dioxide capture from post combustion process could be applied for reducing green house gas emissions. Amine absorption is a commercially available technology which is widely used for carbon dioxide separation in petrochemical process. However, two mains compromising of amine absorption are high operating cost and corrosion problem. Recently, Metal organic frameworks (MOFs) have attracted much attention from the researchers due to their unique adsorption/desorption properties, such as functional pores leads to high isosteric heat of adsorption. Furthermore, some MOFs exhibited higher surface area than other porous materials. This review described some basic characteristics of MOFs and further reviewed on their carbon dioxide adsorption capacity from both single and mixture components. Two mains carbon dioxide adsorption/separation mechanisms also commented.

Article Details

How to Cite
Putkham, A. (2017). Application of metal-organic frameworks for carbon dioxide capture. Asia-Pacific Journal of Science and Technology, 18(1), 171–184. Retrieved from https://so01.tci-thaijo.org/index.php/APST/article/view/82829
Section
Research Articles

References

[1] Andrews T, Doutriaux-Boucher M, Boucher O, Forster P. A regional and global analysis of carbon dioxide physiological forcing and its impact on climate. Climate Dynamics. 2011;36(3):783-92.
[2] Lee M-H, Ho C-H, Kim J, Song C-K. Assessment of the changes in extreme vulnerability over East Asia due to global warming. Climatic Change. 2011:1-21.
[3] Friedlingstein P, Houghton RA, Marland G, Hackler J, Boden TA, Conway TJ, et al. Update on CO2 emissions. Nature Geosci. 2010;3(12):811-2.
[4] Kennedy C, Steinberger J, Gasson B, Hansen Y, Hillman T, Havrnek M, et al. Methodology for inventorying greenhouse gas emissions from global cities. Energy Policy. 2010;38(9):4828-37.
[5] IPCC, IPCC Special Report on Carbon Dioxide Capture and Storage, Cambridge University Press, Cambridge. p 108, 2005.
[6] Damen K, Faaij A, Turkenburg W. Pathways towards large-scale implementation of CO2capture and storage: A case study for the Netherlands. International Journal of Greenhouse Gas Control. 2009;3(2):217-36.
[7] Wang M, Lawal A, Stephenson P, Sidders J, Ramshaw C. Post-combustion CO2 capture with chemical absorption: A state-of-the-art review. Chemical Engineering Research and Design. 2011;89(9):1609-24.
[8] Berger AH, Bhown AS. Comparing physisorp-tion and chemisorption solid sorbents for use separating CO2 from fl ue gas using temperature swing adsorption. Energy Procedia. 2011; 4(0):562-7.
[9] Kitagawa S, Kitaura R, Noro S-i. Functional porous coordination polymers. Angewandte Chemie International Edition. 2004;43(18):2334-75.
[10] James SL. Metal-organic frameworks. Chemical Society Reviews. 2003;32(5):276-88.
[11] Abourahma H, Moulton B, Kravtsov V, Zaworotko MJ. Supramolecular isomerism in coordination compounds: nanoscale molecular hexagons and chains. Journal of the American Chemical Society. 2002;124(34):9990-1.
[12] Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J. Reticular synthesis and the design of new materials. Nature. 2003;423(6941):705-14.
[13] Xiang S, Zhou W, Gallegos JM, Liu Y, Chen B. Exceptionally high acetylene uptake in a microporous metal-organic framework with open metal sites. Journal of the American Chemical Society. 2009;131(34):12415-9.[14] Putkham A, Thomas KM. Applications of novel Cu-MOF for hydrogen storage and air separation. The 6th Pure and Applied Chemistry International Conference (PACCON2012); 2012 January 11-13, 2012; Chiang Mai , Thailand: Department of Chemistry, Faculty of Science, Chiang Mai University and Chemical Society of Thailand; 2012. p. 1045-8.
[15] Putkham A. Kinetic molecular sieving of oxygen, nitrogen and argon on metal organic frameworks and a carbon molecular sieve. 9th International Symposium on the Characterisation of Porous Solids - COPS 9; 5th- 8th June Dresden, Germany: DECHEMA Society for Chemical Technology and Biotechnology 2011. p. 150.
[16] Putkham A. Synthesis, characterisation and gas adsorption studies for metal organic framework materials, Ph.D. thesis. Newcastle upon Tyne: Newcastle University; 2010.
[17] Fletcher AJ, Uygur Y, Thomas KM. Role of surface functional groups in the adsorption kinetics of water vapor on microporous activated carbons. The Journal of Physical Chemistry C. 2007;111(23):8349-59.
[18] Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, et al. Hydrogen storage in microporous metal-organic frameworks. Science. 2003 May 16, 2003;300(5622):1127-9.
[19] Thomas KM. Hydrogen adsorption and storage on porous materials. Catalysis Today. 2007;120(3-4):389-98.[20] Mueller U, Schubert M, Teich F, Puetter H, Schierle-Arndt K, Pastre J. Metal-organic frameworks-prospective industrial applications. Journal of Materials Chemistry. 2006;16(7):626-36.
[21] Furukawa H, Ko N, Go YB, Aratani N, Choi SB, Choi E, et al. Ultrahigh porosity in petal-organic frameworks. Science. 2010;329(5990):424-8.
[22] Li J-R, Ma Y, McCarthy MC, Sculley J, Yu J, Jeong H-K, et al. Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coordination Chemistry Reviews. 2011;255(15-16):1791-823.
[23] Millward AR, Yaghi OM. Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. Journal of the American Chemical Society. 2005;127(51):17998-9.
[24] Rouquerol F, Rouquerol J, Sing KSW. Adsorption by powders, porous solids. London: Academic Press 1999. p 478.
[25] Yang RT. Adsorbents: Fundamentals and Applications: Wiley-Interscience 2003. p 478.
[26] Park M, Moon D, Yoon JW, Chang J-S, Lah MS. A metal-organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior. Chemical Communications. 2009(15):2026-8.
[27] Bourrelly S, Llewellyn PL, Serre C, Millange F, Loiseau T, Ferey G. Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47. Journal of the American Chemical Society. 2005;127(39):13519-21.
[28] Millward AR, Yaghi OM. Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. Journal of the American Chemical Society. 2005;127(51):17998-9.
[29] Llewellyn PL, Bourrelly S, Serre C, Vimont A, Daturi M, Hamon L, et al. High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101. Langmuir. 2008;24(14):7245-50
[30] Zheng B, Bai J, Duan J, Wojtas L, Zaworotko MJ. Enhanced CO2 binding affi nity of a high-uptake rht-type metal-organic framework decorated with acylamide groups. Journal of the American Chemical Society. 2012;133(4):748-51.
[31] Xiang Z, Leng S, Cao D. Functional group modifi cation of metal-organic frameworks for CO2 capture. The Journal of Physical Chemistry C. 2012;116(19):10573-9.
[32] Liu J, Tian J, Thallapally PK, McGrail BP. Selective CO2 capture from flue gas using metal-organic frameworks: A fixed bed study. The Journal of Physical Chemistry C. 2012;116(17):9575-81.
[33] Küsgens P, Rose M, Senkovska I, Fröde H, Henschel A, Siegle S, et al. Characterization of metal-organic frameworks by water adsorption. Microporous and Mesoporous Materials. 2009;120(3):325-30.
[34] Liu H, Zhao Y, Zhang Z, Nijem N, Chabal YJ, Zeng H, et al. The effect of methyl functionalizationon microporous metal-organic frameworks’ capacity and binding energy for carbon dioxide adsorption. Advanced Functional Materials. 2011;21(24):4754-62.
[35] Plaza MG, Pevida C, Arenillas A, Rubiera F, Pis JJ. CO2 capture by adsorption with nitrogen enriched carbons. Fuel. 2007;86(14):2204-12.
[36] Chen B, Zhao X, Putkham A, Hong K, Lobkovsky EB, Hurtado EJ, et al. Surface interactions and quantum kinetic molecular sieving for H2 and D2adsorption on a mixed metal-organic framework material. Journal of the American Chemical Society. 2008;130(20):6411-23.
[37] Chen B, Ma S, Hurtado EJ, Lobkovsky EB, Zhou H-C. A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules. Inorganic Chemistry. 2007;46(21):8490-2.
[38] Chen B, Ma S, Zapata F, Fronczek FR, Lobkovsky EB, Zhou H-C. Rationally Designed Micropores within a Metal-Organic Frame-work for Selective Sorption of Gas Molecules. Inorganic Chemistry. 2007;46(4):1233-6.
[39] Bastin L, Barcia PS, Hurtado EJ, Silva JAC, Rodrigues AE, Chen B. A microporous metal-organic framework for separation of CO2/N2 and CO2/CH4 by fi xed-bed adsorption. The Journal of Physical Chemistry C. 2008;112(5):1575-81.
[40] Nakagawa K, Tanaka D, Horike S, Shimomura S, Higuchi M, Kitagawa S. Enhanced selectivity of CO2 from a ternary gas mixture in an interdigitated porous framework. Chemical Communications. 2010;46(24):4258-60.